Zetamix Black Zirconia
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Zetamix Black Zirconia

ZETAMIX-BZIRCONIA-175-500
349.00 € 349.00 €
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In stock 2 units available for immediate shipping.
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Approximate delivery date: Monday 18 November
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Nanoe is a renowned French company founded in 2008 and specialised in the production of innovative materials. It stands out mainly in the production of ceramic powders, with a production capacity of more than 100 tons of high purity ceramic powder per year.

Video 1: Meet Zetamix By Nanoe. Source: Nanoe.

Taking advantage of the high degree of know-how in the field of ceramics, in 2018 they created the Zetamix brand, the first brand of filaments with technical ceramics aimed at producing all-ceramic parts in an accessible and affordable way.

Nanoe currently has three ceramic filaments for technical applications: White Zirconia, Black Zirconia and Alumina.

White
zirconia		 Black
zirconia		 Alumina 316L H13
Impact and
flexural strength		 starstarstar starstar star starstarstarstar starstarstarstar
Wear
resistance		 starstarstar starstar starstarstar star star
Electrical
insulation		 star star starstarstar
Chemical Inertia starstarstar starstar starstarstarstar starstar star
Estheticism starstarstar starstarstar star
High temperature
resistance		 starstar starstar starstarstarstar star starstar
Thermal
conduction		 star star starstarstarstar starstarstar starstarstar
Image 1: Comparison of Zetamix ceramic filaments. Source: Nanoe

Zetamix Black Zirconia is a filament consisting of 85 % by weight of stabilised black zirconia powder and 15 % by weight of binder. Black zirconia is one of the most common substitutes for black diamond in jewellery. Its high hardness and the possibility of being polished to a shiny finish make it an economical and quality alternative.

Ajedrez circonia negra

Image 2: Piece printed with Zetamix Black Zirconia, sintered and polished. Source: Nanoe

This is why Zetamix Black Zirconia is a perfect filament to produce jewellery pieces impossible to obtain by traditional cutting.

pieza circonia negra

Imagen 3: Pieza impresa con Zetamix Circonia Negra y sinterizada. Fuente: Nanoe

Zetamix ceramic filaments make it possible to obtain fully ceramic parts easily in three steps:

  • Printing: Zetamix ceramic filaments can be easily printed on virtually any direct extruder printer, as they require printing temperatures between 150 and 180 ºC and a base temperature of 40 ºC.

impresion

Image 4: impression of a ceramic piece. Source: Nanoe
  • Debinding: Debinding consists of two stages, chemical debinding in acetone using an ultrasonic bath such as Zetadebinder and thermal debinding prior to sintering.
  • Sintering: Finally, the part is sintered by heat treatment to obtain a completely ceramic part.

Muestras circonia negra

Image 5: Parts printed in Zetamix Black Zirconia and sintered. Source: Nanoe

Ceramic printing has been a great challenge due to its complexity and high cost. Thanks to Zetamix ceramic filaments, it is possible to obtain complex all-ceramic parts in an economical and simple way.

Zetamix Webinar

General information
Manufacturer Nanoe (Zetamix)
Material Ceramic + binder
Format 500 g
Density 3.5 g/cm³
Filament diameter 1.75 / 2.85 mm
Filament length (Ø 1.75 mm - 0.5 Kg) ± 83 m / (Ø 2.85 mm - 0.5 Kg) ± 31 m
Amount of filler (volume) 50 %
Amount of filler (mass) 85 %

Printing properties
Printing temperature 170 ºC
Print bed temperature 40 ºC
Cooling fan 100 %
Recommended printing speed 30 mm/s
Recommended nozzle diameter Min. 0.4 mm

Mechanical properties
Elongation at break - %
Tensile strength - MPa
Tensile modulus - MPa
Flexural strength - MPa
Flexural modulus - MPa
Surface hardness Shore 45 D

Thermal properties
Softening temperature - ºC

Sintering properties
Container Refractory crucible
Refractory powder Alumina
Maximum temperature 1475 ºC

Specific properties
Radiation protection (without sintering) ✗

Other
HS Code 8108.9060

It is recommended to carefully follow the design guide available in the download tab when designing the parts to be made with Zetamix Alumina.

Printing:

When printing, the following parameters must be applied:

Printing temperature: 170 ºC
Base temperature: 40 ºC
Nozzle size: 0.4 - 1.0 mm
Coating height: 0.3 - 0.1 (0.15 recommended)
Print speed: 20 - 35 mm/s
Shrinkage: 1 mm to 20 mm/s
Perimeters: At least 2
Filling: 5 % - 100 % Filling: 5 % - 100 % Filling: 5 % - 100 % Filling: 5 % - 100
Top and bottom wall thicknesses: At least 1 mm
Substrates: Supports: Supports in the same material and in soluble materials.
Adhesion to backing: Glass backing and Magigoo adhesive recommended.

Zetamix ceramic filaments are only compatible with direct extruders. The spool should be placed on top of the printer so that the path between the spool and the extruder is as straight as possible.

It is advisable to reduce the extruder tension to a minimum to prevent the filament from deteriorating.

Debinding:

Debinding consists of two stages, a chemical and a thermal stage.

Chemical debinding: The part must be treated for at least 2 hours in an ultrasonic bath with acetone at 40 ºC. Afterwards, the piece must be left to air dry for at least 2 hours. If the treatment has been successful, the piece should lose 5% of its weight.

Heat debinding: The pieces must be placed in a crucible with refractory powder to support the shrinkage of the piece and to serve as a support during the process. A heat treatment should then be applied consisting of heating the parts from 20 ºC to 500 ºC at a rate of 8 ºC/hr. For small parts, the debinding time can be reduced by applying the following heat treatment:

Initial TemperatureFinal TemperatureSpeed
2012535 ºC/h
12520050 ºC/h
20021522 ºC/h
21525011 ºC/h
25028020 ºC/h
2803208 ºC/h
32051024 ºC/h

Sintering:

After debinding, the part must be sintered by applying the following heat treatment:

  • Heat from 20 ºC up to 1475 ºC at a speed of 50 ºC/h.
  • Hold at 1475 ºC for 2 hours
  • Cool to room temperature at a rate of 100 ºC/h

Featured properties

Printing temperature
170 ºC
Filament diameter
1.75 / 2.85 mm
Density
3,5 g/cm³

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