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Nanoe is a renowned French company founded in 2008 and specialised in the production of innovative materials. It stands out mainly in the production of ceramic powders, with a production capacity of more than 100 tons of high purity ceramic powder per year.
Taking advantage of the high degree of know-how in the field of ceramics, in 2018 they created the Zetamix brand, the first brand of filaments with technical ceramics aimed at producing all-ceramic parts in an accessible and affordable way.
Nanoe currently has three ceramic filaments for technical applications: White Zirconia, Black Zirconia and Alumina.
White zirconia | Black zirconia | Alumina | 316L | H13 | |
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Impact and flexural strength |
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Wear resistance |
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Electrical insulation |
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Chemical Inertia | |||||
Estheticism | |||||
High temperature resistance |
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Thermal conduction |
Zetamix Black Zirconia is a filament consisting of 85 % by weight of stabilised black zirconia powder and 15 % by weight of binder. Black zirconia is one of the most common substitutes for black diamond in jewellery. Its high hardness and the possibility of being polished to a shiny finish make it an economical and quality alternative.
This is why Zetamix Black Zirconia is a perfect filament to produce jewellery pieces impossible to obtain by traditional cutting.
Zetamix ceramic filaments make it possible to obtain fully ceramic parts easily in three steps:
Ceramic printing has been a great challenge due to its complexity and high cost. Thanks to Zetamix ceramic filaments, it is possible to obtain complex all-ceramic parts in an economical and simple way.
It is recommended to carefully follow the design guide available in the download tab when designing the parts to be made with Zetamix Alumina.
When printing, the following parameters must be applied:
Printing temperature: 170 ºC
Base temperature: 40 ºC
Nozzle size: 0.4 - 1.0 mm
Coating height: 0.3 - 0.1 (0.15 recommended)
Print speed: 20 - 35 mm/s
Shrinkage: 1 mm to 20 mm/s
Perimeters: At least 2
Filling: 5 % - 100 % Filling: 5 % - 100 % Filling: 5 % - 100 % Filling: 5 % - 100
Top and bottom wall thicknesses: At least 1 mm
Substrates: Supports: Supports in the same material and in soluble materials.
Adhesion to backing: Glass backing and Magigoo adhesive recommended.
Zetamix ceramic filaments are only compatible with direct extruders. The spool should be placed on top of the printer so that the path between the spool and the extruder is as straight as possible.
It is advisable to reduce the extruder tension to a minimum to prevent the filament from deteriorating.
Debinding consists of two stages, a chemical and a thermal stage.
Chemical debinding: The part must be treated for at least 2 hours in an ultrasonic bath with acetone at 40 ºC. Afterwards, the piece must be left to air dry for at least 2 hours. If the treatment has been successful, the piece should lose 5% of its weight.
Heat debinding: The pieces must be placed in a crucible with refractory powder to support the shrinkage of the piece and to serve as a support during the process. A heat treatment should then be applied consisting of heating the parts from 20 ºC to 500 ºC at a rate of 8 ºC/hr. For small parts, the debinding time can be reduced by applying the following heat treatment:
Initial Temperature | Final Temperature | Speed |
---|---|---|
20 | 125 | 35 ºC/h |
125 | 200 | 50 ºC/h |
200 | 215 | 22 ºC/h |
215 | 250 | 11 ºC/h |
250 | 280 | 20 ºC/h |
280 | 320 | 8 ºC/h |
320 | 510 | 24 ºC/h |
After debinding, the part must be sintered by applying the following heat treatment:
General information | |
---|---|
Manufacturer | Nanoe (Zetamix) |
Material | Stabilised black zirconia powder and thermoplastic binder |
Format | Spool of 500 g |
Density | 3.5 g/cm3 |
Amount of metal (volume) | 50 % |
Amount of metal (mass) | 85 % |
Diameter of filament | 1.75 or 2.85 mm |
Diameter tolerance | |
Filament length | ±83 m (Ø 1.75 mm-0.5Kg) ±31 m (Ø 2.85 mm-0.5Kg) |
Color | Black |
RAL/Pantone | - |
Print settings | |
Printing temperature | 170 ºC |
Temperatura de base/cama | 40 ºC |
FilaWarmer temperature (1) | - |
Print bed temperature | - |
Chamber temperature | 100% |
Print speed | 30 mm/s |
Nozzle diameter | ≥0.4 mm |
Recommended infill | 5 %-100 % |
Sintering properties | |
Container | Refractory Crucible |
Refractory powder | Alumina |
Maximum temperature | 1475 ºC |
Mechanical properties | |
Izod impact strength | - |
Charpy impact strength | - |
Elongation at break | - |
Tensile strength | - |
Tensile Modulus | - |
Flexural strength | - |
Flexural modulus | - |
Surface hardness | - |
Thermal properties | |
Softening temperature | - |
Melting temperature | - |
Specific properties | |
Transparency | Opaque |
Radiation protection (without sintering) | No |
Additional Information | |
HS Code | 8108.9060 |
Diameter coil (outer) | - |
Diameter coil (inner hole) | - |
Coil Width | - |
* The typical values detailed in this table should be considered as a reference. Actual values may vary depending on the 3D printer model used, part design and printing conditions. We recommend confirming the results and final properties with own tests. For more information you should consult the technical data sheet of the product.
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